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31.
Ionela-Dorina Dumbrava Calin-Cristian Cormos 《International Journal of Hydrogen Energy》2021,46(45):23149-23163
Hydrogen production by biogas conversion represent a promising solution for reduction of fossil CO2 emissions. In this work, a detailed techno-economic analysis was performed for decarbonized hydrogen production based on biogas conversion using calcium and chemical looping cycles. All evaluated concepts generate 100,000 Nm3/h high purity hydrogen. As reference cases, the biogas steam reforming design without decarbonization and with CO2 capture by gas-liquid chemical absorption were also considered. The results show that iron-based chemical looping design has higher energy efficiency compared with the gas-liquid absorption case by 2.3 net percentage points as well as a superior carbon capture rate (99% vs. 65%). The calcium looping case shows a lower efficiency than chemical scrubbing, with about 2.5 net percentage points, but the carbon capture rate is higher (95% vs. 65%). The hydrogen production cost increases with decarbonization, the calcium looping shows the most favourable situation (37.14 €/MWh) compared to the non-capture steam reforming case (33 €/MWh) and MDEA and iron looping cases (about 42 €/MWh). The calcium looping case has the lowest CO2 avoidance cost (10 €/t) followed by iron looping (20 €/t) and MDEA (31 €/t) cases. 相似文献
32.
Hydrogel-based nanofibers or vice versa are a relatively new class of nanomaterials, in which hydrogels are structured in nanofibrous form. Structure and size of the material directly governs its functionality, therefore, in hydrogel science, the nanofibrous form of hydrogels enables its usage in targeted applications. Hydrogel nanofiber system combines the desirable properties of both hydrogel and nanofiber like flexibility, soft consistency, elasticity, and biocompatibility due to high water content, large surface area to volume ratio, low density, small pore size and interconnected pores, high stiffness, tensile strength, and surface functionality. Swelling behavior is a critical property of hydrogels that is significantly increased in hydrogel nanofibers due to their small size. Electrospinning is the most popular method to fabricate “hydrogel nanofibers,” while other processes like self-assembly, solution blowing and template synthesis also exist. Merging the characteristics of both hydrogels and nanofibers in one system allows applications in drug delivery, tissue engineering, actuation, wound dressing, photoluminescence, light-addressable potentiometric sensor (LAPS), waterproof breathable membranes, and enzymatic immobilization. Treatment of wastewater, detection, and adsorption of metal ions are also emerging applications. In this review paper, we intend to summarize in detail about electrospun “hydrogel nanofiber” in relation to its synthesis, properties, and applications. 相似文献
33.
《International Journal of Hydrogen Energy》2022,47(54):22981-22992
In this study, a three-dimensional model was established using the lattice Boltzmann method (LBM) to study the internal ice melting process of the gas diffusion layer (GDL) of the proton exchange membrane fuel cell (PEMFC). The single-point second-order curved boundary condition was adopted. The effects of GDL carbon fiber number, growth slope of the number of carbon fibers and carbon fiber diameter on ice melting were studied. The results were revealed that the temperature in the middle and lower part of the gradient distribution GDL is significantly higher than that of the no-gradient GDL. With the increase of the growth slope of the number of carbon fiber, the temperature and melting rate gradually increase, and the position of the solid-liquid interface gradually decreases. The decrease in the number of carbon fibers has a similar effect as the increase in the growth slope of the number of carbon fibers. In addition, as the diameter of the carbon fiber increases, the position of the solid-liquid interface gradually decreases first and then increases. 相似文献
34.
药物相互作用改变了剂量效应关系,可能会降低疗效或增加毒性,是临床应用中合并用药治疗时重要的考虑因素。预测具有临床意义的药物相互作用是药物研发过程中获益风险评估的重要环节。本文概述了药物研发过程中药物相互作用研究的目的和意义,体内和体外研究的主要内容;梳理分析了2020年国家药品监督管理局(National Medical Products Administration, NMPA)和美国食品药品监督管理局(Food and Drug Administration, FDA)批准上市的新药药物相互作用研究情况,旨在为我国药物研发过程中药物相互作用研究及其监管审评提供参考。 相似文献
35.
文章介绍了海外某大型火力发电厂发生的一起发电机定子接地故障的分析和处理过程,对发电厂类似故障的处理和海外发电厂的运行和维护提供了参考。 相似文献
36.
Dr. Md Kausar Raza Aisha Noor Dr. Paresh Kumar Samantaray 《Chembiochem : a European journal of chemical biology》2021,22(23):3270-3272
Individually, photoredox catalysis (PC) and photodynamic therapy (PDT) are well-established concepts that have experienced a remarkable resurgence in recent years, leading to significant progress in organic synthesis for PC and clinical approval of anticancer drugs for PDT. But, very recently, new photoredox catalyst systems based on Ir(III) and Ru(II) complexes have garnered significant interest because they can simultaneously be used as PDT agents apart from their demonstrated PC activity. This highlight discusses the unique PC behavior of emerging Ir(III)- and Ru(II)-based systems while also examining their potential PDT activity in cancer treatment. 相似文献
37.
Yujie Chen Yiping Song Zhen Zhang Yali Chen Qiliang Deng Shuo Wang 《Advanced functional materials》2021,31(41):2104885
Various products, including foods and pharmaceuticals, are sensitive to temperature fluctuations. Thus, temperature monitoring during production, transportation, and storage is critical. Facile indicators are required to monitor temperature conditions via color changes in real time. This study aimed to prepare and apply thiol-functionalized covalent organic frameworks (COFs) as a novel indicator for monitoring thermal history and temperature abuse. The COFs underwent obvious color changes from bright yellow to purple after exposure to different temperatures for varying durations. The reaction kinetics are analyzed under isothermal conditions, which reveal that the order of reaction rates is k−20°C < k4°C < k20°C < k35°C < k55°C. The activation energy (Ea) of the COFs is calculated using the Arrhenius equation as 50.71 kJ moL−1. The COFs are capable of sensitive color changes and offer a broad temperature tracking range, thereby demonstrating their application potential for the monitoring of temperature and time exposure history during production, transportation, and storage. This excellent performance thermal history indicator also shows promise for expanding the application field of COFs. 相似文献
38.
39.
Makoto Yamaguchi 《应用聚合物科学杂志》2021,138(14):50172
Perfluorosulfonic acid ionomer membranes have been widely used as proton conducting membranes in various electrochemical processes such as polymer electrolyte fuel cells and water electrolysis. While their thermal stability has been studied by thermogravimetry and analysis of low molecular weight products, their decomposition mechanism is little understood. In this study a newly developed methodology of thermal desorption and pyrolysis in combination with direct analysis in real time mass spectrometry is applied for Nafion membrane. An ambient ionization source and a high-resolution time-of-flight mass spectrometer enabled unambiguous assignment of gaseous products. Thermal decomposition is initiated by side chain detachment above 350°C, which leaves carbonyls on the main chain at the locations of the side chains. Perfluoroalkanes are released above 400°C by main chain scission and their further decomposition products dominate above 500 °C. DFT calculation of reaction energies and barrier heights of model compounds support proposed decomposition reactions. 相似文献
40.
《Ceramics International》2022,48(1):769-775
Brittle materials generally exhibit size effects, and the mechanical properties of these materials degrade significantly with an increase in size. However, the mathematical law governing the attenuation degree of mechanical properties with the increase in size is still unknown. In this study, maximum loads of differently sized ceramic test strips were subjected to three point bending tests under two working conditions of equal spans and span amplifications, respectively. Subsequently, the theoretical maximum loads of materials were calculated using the finite element method (FEM). By calculating the difference between the calculated values and the actual maximum loads, the attenuation of mechanical properties of ceramic samples were observed. The results show that the theoretical mechanical properties and the performance attenuation caused by the size effect tend to increase according to the following equation: y=ax3+bx2+cx+d. Therefore, mechanical properties and performance attenuation of any sample exhibiting a size within the experimental range can be predicted by a mathematical law, which was obtained through mechanical tests results of four samples with different sizes. The obtained mathematical law holds great significance for predicting the mechanical properties of materials under size effects. 相似文献